Levels and fingerprints of chlorinated aromatic hydrocarbons in fly ashes from the typical industrial thermal processes: Implication for the co-formation mechanism.

Municipal solid waste incineration (MSWI) and iron and steel making plants are two of important sources of chlorinated aromatic hydrocarbons (CAHs). In this study, the typical CAHs including polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs), polychlorinated naphthalenes (PCNs) and chlorinated polycyclic aromatic hydrocarbons (Cl-PAHs) in fly ash samples collected from MSWI, iron ore sintering (IOS) and steel smelting (SS) plants were simultaneously identified and quantified. The total concentrations of quantified CAHs in different fly ashes showed a large variation (5.88-4255 ng/g). Cl-PAHs were found to be predominant CAH species in most of fly ash samples, and the concentrations of mono-chlorinated PAHs in all fly ashes were obviously higher than those of di-chlorinated PAHs. The fingerprints of CAHs in MSWI fly ashes were mainly characterized by the high content of PCDDs, especially the hexa-CDD homologue. However, in IOS and SS fly ashes, tetra- to hexa-CDF homologues showed the higher abundance, and tetra-to octa-CDFs predominated over tetra- to octa-CDDs by factors of 3-26. The strong concentration correlations were observed between tetra- to octa-CDF homologues, middle-chlorinated PCN and PCB homologues, between tetra- to octa-CDD homologues, between low-chlorinated PCB and PCN homologues, between di-chlorinated PAH homologues, and between deca-CB and highly chlorinated PCN homologues. These results implied that the main formation mechanism of CAHs might be significantly varied with the change of chlorination degree and aromatic ring structure.