Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, P.O. Box 272, No. 130 Meilong Road, Shanghai, 200237, People's Republic of China.
Environ Sci Pollut Res Int. 2019 May;26(14):14171-14177. doi: 10.1007/s11356-019-04776-0. Epub 2019 Mar 11.
The preparation of coal water slurry (CWS) using wastewater, which contains inorganic and organic components, is one method of wastewater utilization. In this study, the effect of inorganic salts on the viscosity of CWS was examined. The results show that monovalent salts (NaCl, KCl) decreased the viscosity of CWS. The viscosity of CWS was not affected by bivalent salts (CaCl, MgCl). However, CWS combined with trivalent salt (AlCl) sharply increased the viscosity. The zeta potential of CWS with inorganic salts increased which can enhance the electric repulsion and beneficial to reduce the viscosity. The content of free water in CWS with trivalent salt decreased, and the freedom of the free water in CWS with trivalent salt decreased which were all bad to the viscosity and the adsorption of the dispersant on the particles. Compared with the surface polarity of the particles without inorganic salts, the surface polarity of the particles with divalent salts was similar to those without inorganic salts. Under the comprehensive influence, divalent salt has little effect on the viscosity of CWS.
利用废水制备水煤浆(CWS)是废水利用的一种方法,废水中含有无机和有机成分。本研究考察了无机盐对 CWS 粘度的影响。结果表明,一价盐(NaCl、KCl)降低了 CWS 的粘度,二价盐(CaCl、MgCl)对 CWS 的粘度没有影响。然而,CWS 与三价盐(AlCl)结合会急剧增加粘度。无机盐会增加 CWS 的动电位,增强电动排斥力,有利于降低粘度。CWS 中三价盐的游离水含量减少,游离水的自由度降低,这对粘度和分散剂在颗粒上的吸附都不利。与不含无机盐的颗粒的表面极性相比,含二价盐的颗粒的表面极性与不含无机盐的颗粒相似。在综合影响下,二价盐对 CWS 的粘度影响较小。