Ahmed Mukhtiar, Faisal Muhammad, Ihsan Ayesha, Naseer Muhammad Moazzam
Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan.
Analyst. 2019 Apr 8;144(8):2480-2497. doi: 10.1039/c8an01801d.
Recently, water contamination caused by metal ions has become one of the most serious problems as it has caused several deaths and socioeconomic problems around the world. Hence, the fast and accurate detection of metal ions in aqueous media has become the most important area of research; from time to time, new probes have been designed for this purpose. Among the previously reported sensors, probes based on fluorescent organic nanoparticles (FONs) have been gaining tremendous attention due to their ease of preparation/fabrication, synthetic diversity according to targeted metal ions, quick response, high selectivity toward different analytes at lower concentrations, tenable optical properties, and less toxicity. This review comprises two main sections, wherein we have tried to summarize the key progresses made in this field. The first section summarizes the literature dealing with FON-based chemosensors, which are used for the detection of transition metal ions of silver, copper, chromium, cadmium, mercury, iron, and zinc. The second section focuses on FON-based chemosensors that have been used for the detection of main group metal ions, namely, cesium, aluminum, strontium, lithium, and tin. Further, this review provides an adequate amount of information about the mechanism of metal ion sensing with FONs. It is expected that this review can provide sufficient information about this area of research and will be useful in fruitful progress in this field in the future.
近年来,金属离子造成的水污染已成为最严重的问题之一,因为它在全球范围内导致了多起死亡事件和社会经济问题。因此,快速、准确地检测水介质中的金属离子已成为最重要的研究领域;为此,人们不时设计出新的探针。在先前报道的传感器中,基于荧光有机纳米颗粒(FONs)的探针因其易于制备/制造、可根据目标金属离子进行合成多样性、响应迅速、对低浓度不同分析物具有高选择性、光学性质稳定以及毒性较小而备受关注。本综述包括两个主要部分,我们试图总结该领域取得的关键进展。第一部分总结了有关基于FON的化学传感器的文献,这些传感器用于检测银、铜、铬、镉、汞、铁和锌等过渡金属离子。第二部分重点介绍了用于检测主族金属离子(即铯、铝、锶、锂和锡)的基于FON的化学传感器。此外,本综述提供了关于FONs检测金属离子机制的足够信息。预计本综述能够提供有关该研究领域的充分信息,并将有助于该领域在未来取得丰硕进展。