Shellaiah Muthaiah, Sun Kien Wen
Department of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu 300, Taiwan.
Nanomaterials (Basel). 2021 Dec 27;12(1):64. doi: 10.3390/nano12010064.
Diamond electrodes have long been a well-known candidate in electrochemical analyte detection. Nano- and micro-level modifications on the diamond electrodes can lead to diverse analytical applications. Doping of crystalline diamond allows the fabrication of suitable electrodes towards specific analyte monitoring. In particular, boron-doped diamond (BDD) electrodes have been reported for metal ions, anions, biomolecules, drugs, beverage hazards, pesticides, organic molecules, dyes, growth stimulant, etc., with exceptional performance in discriminations. Therefore, numerous reviews on the diamond electrode-based sensory utilities towards the specified analyte quantifications were published by many researchers. However, reviews on the nanodiamond-based electrodes for metal ions and anions are still not readily available nowadays. To advance the development of diamond electrodes towards the detection of diverse metal ions and anions, it is essential to provide clear and focused information on the diamond electrode synthesis, structure, and electrical properties. This review provides indispensable information on the diamond-based electrodes towards the determination of metal ions and anions.
金刚石电极长期以来一直是电化学分析物检测中广为人知的候选材料。对金刚石电极进行纳米和微米级修饰可带来多种分析应用。对晶体金刚石进行掺杂能够制造出适用于特定分析物监测的电极。特别是,硼掺杂金刚石(BDD)电极已被报道可用于检测金属离子、阴离子、生物分子、药物、饮料危害物、农药、有机分子、染料、生长刺激剂等,在鉴别方面具有卓越性能。因此,许多研究人员发表了大量关于基于金刚石电极的针对特定分析物定量的传感应用的综述。然而,目前关于基于纳米金刚石的用于检测金属离子和阴离子的电极的综述仍然难以获取。为推动金刚石电极在检测多种金属离子和阴离子方面的发展,提供关于金刚石电极合成、结构和电学性质的清晰且有针对性的信息至关重要。本综述提供了关于基于金刚石的电极用于测定金属离子和阴离子的不可或缺的信息。