利用线性构筑块的二元混合物通过分子间卤键形成六方排列：STM 研究。
Hexagonal array formation by intermolecular halogen bonding using a binary blend of linear building blocks: STM study.
机构信息
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
出版信息
Chem Commun (Camb). 2019 Apr 7;55(27):3955-3958. doi: 10.1039/c9cc00532c. Epub 2019 Mar 15.
PMID:30874258
Abstract
Hexagonal arrays were fabricated via intermolecular halogen bonding between two linear molecular building blocks in a bicomponent blend. The substitution position of the pyridine N atom involved in the halogen bond plays an important role in the formation of the hexagonal structures.
摘要
通过两种线性分子构建块在双组分共混物之间的分子间卤键作用，制备了六方排列。参与卤键的吡啶 N 原子的取代位置在六方结构的形成中起着重要作用。
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