Xing Yao, Zhao Degang, Jiang Desheng, Liu Zongshun, Zhu Jianjun, Chen Ping, Yang Jing, Liang Feng, Liu Shuangtao, Zhang Liqun
State Key Laboratory of Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Science, Beijing, 100083, China.
College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing, 100049, China.
Nanoscale Res Lett. 2019 Mar 12;14(1):88. doi: 10.1186/s11671-019-2919-9.
The InGaN/GaN multi-quantum wells (MQWs) are prepared at the same condition by metal-organic chemical vapor deposition (MOCVD) except the thickness of cap layers additionally grown on each InGaN well layer. The photoluminescence (PL) intensity of the thin cap layer sample is much stronger than that of thicker cap layer sample. Interestingly, the thick cap layer sample has two photoluminescence peaks under high excitation power, and the PL peak energy-temperature curves show an anomalous transition from reversed V-shaped to regular S-shaped with increasing excitation power. Meanwhile, it exhibits a poorer thermal stability of thick cap layer sample under higher excitation power than that under lower excitation power. Such an untypical phenomenon is attributed to carrier redistribution between the two kinds of localized states which is induced by the inhomogeneous distribution of indium composition in thick cap layer sample. Furthermore, the luminescence of deep localized states has a better thermal stability, and the luminescence of shallow localized states has a poor thermal stability. In fact, such a severer inhomogeneous indium distribution may be caused by the degradation of subsequent epitaxial growth of InGaN/GaN MQWs region due to longer low-temperature GaN cap layer growth time.
通过金属有机化学气相沉积(MOCVD)在相同条件下制备InGaN/GaN多量子阱(MQW),只是在每个InGaN阱层上额外生长的盖帽层厚度不同。薄盖帽层样品的光致发光(PL)强度比厚盖帽层样品的要强得多。有趣的是,厚盖帽层样品在高激发功率下有两个光致发光峰,并且PL峰能量-温度曲线随着激发功率的增加呈现出从反向V形到常规S形的异常转变。同时,厚盖帽层样品在高激发功率下比在低激发功率下表现出更差的热稳定性。这种不典型的现象归因于厚盖帽层样品中铟成分的不均匀分布所引起的两种局域态之间的载流子重新分布。此外,深局域态的发光具有更好的热稳定性,而浅局域态的发光具有较差的热稳定性。实际上,这种更严重的铟分布不均匀可能是由于InGaN/GaN MQW区域后续外延生长的退化导致的,这是由于低温GaN盖帽层生长时间较长。