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基于银沸石复合材料的发光二极管:电致发光和电荷输运的起源。

Silver Zeolite Composite-Based LEDs: Origin of Electroluminescence and Charge Transport.

机构信息

Chem&Tech-Molecular Imaging and Photonics , Katholieke Universiteit Leuven , Celestijnenlaan 200F , Leuven B-3001 , Belgium.

Departamento de Química Física, Facultad de Farmacia , Universidad de Castilla-La Mancha , Campus Universitario , Albacete 02071 , Spain.

出版信息

ACS Appl Mater Interfaces. 2019 Apr 3;11(13):12179-12183. doi: 10.1021/acsami.8b20534. Epub 2019 Mar 20.

Abstract

In this contribution, we report on the first time use of silver-exchanged zeolites embedded in the nonconductive polystyrene (PS) and their use as hybrid emitters in light-emitting diodes (ZEOLEDs). The turn on voltage and EL intensity are strongly dependent on the concentration of metal clusters. It is shown that the key to optimize this technology is improving the zeolite anode contact. Such an optimized device based on cheap abundant materials could provide an alternative for the commercial phosphor converted LEDs. A ZEOLED with a voltage polarity dependent color is demonstrated.

摘要

在本贡献中,我们首次报告了负载在不导电聚苯乙烯(PS)中的银交换沸石的应用,并将其作为混合发射器应用于发光二极管(ZEOLED)中。开启电压和电致发光强度强烈依赖于金属簇的浓度。结果表明,优化该技术的关键是改善沸石阳极的接触。这种基于廉价丰富材料的优化器件可为商业荧光粉转换 LED 提供替代方案。我们展示了一种具有电压极性相关颜色的 ZEOLED。

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