Applied Chemistry Department, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 211100, China.
Chem Commun (Camb). 2019 Apr 4;55(29):4137-4149. doi: 10.1039/c9cc00273a.
Smart windows are a promising solution to improve energy-saving efficiency and indoor comfort due to their potential functionalities including solar modulation, coloration, self-cleaning, self-power, and moisture scavenging. Recently, smart windows constructed by a supramolecular strategy have attracted increasing attention due to the inherent dynamic, reversible and adaptive properties of noncovalent interactions, which can endow the fabricated smart windows with desired fascinating functionalities. In this review, emerging supramolecular strategy-based materials are outlined and their applications for fabricating smart windows are summarized. Mechanisms and properties of the functional supramolecular materials are demonstrated, especially their solar modulation ability and color change effect. Challenges and opportunities for the supramolecular strategy-based materials are also discussed for future innovation in the development of ideal smart windows.
智能窗户因其具有太阳能调节、着色、自清洁、自供电和吸湿等潜在功能,是提高节能效率和室内舒适度的一种很有前途的解决方案。最近,基于超分子策略的智能窗户由于非共价相互作用的固有动态、可逆和自适应特性而引起了越来越多的关注,这可以赋予所制造的智能窗户所需的迷人功能。在这篇综述中,概述了新兴的基于超分子策略的材料,并总结了它们在制造智能窗户方面的应用。展示了功能超分子材料的机制和特性,特别是它们的太阳能调节能力和颜色变化效果。还讨论了基于超分子策略的材料所面临的挑战和机遇,以期为理想智能窗户的发展带来新的创新。