Simultaneous and fast determination of bisphenol A and diphenyl carbonate in polycarbonate plastics by using excitation-emission matrix fluorescence couples with second-order calibration method.

A new strategy for the determination of bisphenol A (BPA) and diphenyl carbonate (DPC) in polycarbonate plastics has been proposed, combing excitation-emission matrix fluorescence and second-order chemometrics methods. The studied compounds are two of the most frequently used chemical raw materials and intermediates, which is mainly used for bio-chemical products. The method is fast and sensitive as it can avoid tedious pretreatment steps and large amounts of organic solvents consumption. Chemometrics allowed accurate and precise quantification of two target analytes even in the presence of severe spectral overlap, unknown and background interferences, which benefit from "second-order advantages" provided by chemometrics multivariate calibration. Reasonable quantification results were obtained in real plastics samples, with limits of detection for two analytes were 0.04 and 1.18 × 10 ng mL and limits of quantitation were 0.11 and 3.58 × 10 ng mL. In addition, the average recoveries for BPA and DPC were 99.35% and 83.50% with relative standard deviation <2.30%. It was proved that the proposed method can be a useful and sensitive tool to the determination of BPA and DPC in different polycarbonate plastics with a simple sample pretreatment at low cost.