Department of Chemical and Geological Sciences, University of Cagliari, S.S. 554 bivio per Sestu, 09042 Monserrato, Cagliari, Italy.
J Nanosci Nanotechnol. 2019 Aug 1;19(8):4857-4887. doi: 10.1166/jnn.2019.16808.
Nanostructured spinel ferrites with formula MFe2O4 (where M ═ Fe, Co, Mn, Ni, Zn, etc.) represent a class of magnetic materials widely employed in different research fields, due to the possibility of finely tuning the magnetic properties by changing the chemical composition, size, shape, capping agents, etc. Herein, a review of the most common chemical synthesis in liquid media, distinguishing among aqueous and non-aqueous routes, is presented. The experimental procedure together with the mechanism, advantages and disadvantages, and examples are illustrated for each synthetic strategy.
具有化学式 MFe2O4(其中 M ═ Fe、Co、Mn、Ni、Zn 等)的纳米结构尖晶石铁氧体是一类在不同研究领域广泛应用的磁性材料,因为通过改变化学成分、尺寸、形状、封端剂等,可以精细地调整其磁性。本文综述了最常见的在液相中的化学合成方法,区分了水相和非水相路线。对每种合成策略都说明了实验过程、机制、优缺点和实例。