A stable operation method for membrane capacitive deionization systems without electrode reactions at high cell potentials.

A method for operating membrane capacitive deionization (MCDI) systems without electrode reactions at a high cell potential was studied. The charge supplied to the cell was controlled to suppress Faradaic reactions. The maximum allowable charge (MAC) that can be supplied to a carbon electrode without electrode reactions was measured to be 58 C/g. Adsorption experiments were conducted while supplying a charge of 55 C/g (95% of the MAC value) in constant-current (CC) and constant-voltage (CV) mode. The cell potential increased to 1.42 V in CC (1.43-4.29 mA/cm) mode, but the concentration and pH of the effluent were kept constant. In addition, the effluent pH was stable in CV (1.25-2.0 V) mode. The salt adsorption capacities and charge efficiencies were approximately 15.5 mg/g and 92%, respectively, regardless of the current densities and cell potentials applied to the cell. With increasing cell potential, the concentration polarization in the feed stream was intensified, resulting in an increase in cell resistance. It was thought that electrode reactions did not occur at a high cell potential because of the high voltage drop due to the cell resistance. The higher the cell potential (or current density) is, the faster the desalination rate in MCDI operation. It is expected that this operation method applying the MAC concept will contribute to the stable operation of MCDI systems and an improvement in desalination performance.