Effects of different biochar amendments on carbon loss and leachate characterization from an agricultural soil.

Selection of an appropriate biochar as a soil amendment requires a thorough investigation of the effects on soil ecosystems and adjacent water systems via leaching. Different biochar characteristics influence retention or leaching of different soil and biochar components. A lab lysimeter study was conducted to investigate carbon (C) balance and leachate quality with biochar additions. Biochar made from wood pellets (WP) and sewage sludge (SS) produced at 400 °C (WP400 and SS400) and 700 °C (WP700 and SS700), respectively, were applied to silt loam soil at an application rate of 4%. Fluorescence excitation-emission spectrophotometry (EEMs) was utilized to understand the compositional changes in leachate dissolved organic carbon (DOC). Our results show that DOC contributed the largest portion of C leaching loss. The WP treatments increased DOC mass loss, but did not significantly change leachate DOC quality. SS400, in comparison, increased mass loss of DOC and SS700 decreased it probably due to its higher adsorptive capacity to DOC. Unlike WP treatments, SS treatments significantly changed leachate DOC quality. Chemical oxygen demand (COD) was reduced with SS400 and SS700 biochar additions, which is assumed to be related to SS biochar's high oxygen-containing surface functional groups. Reduction in total nitrogen (TN) leaching by WP700 and SS700 treatments might be related to the higher micropore surface area. Over all, our findings imply that changes in the different components of the leachate from biochar-amended soil are related to different biochar properties, such as labile matter content, total surface area, micropore volume and cation exchange capacity.