二（间-间-间）三联苯嵌入的十卟啉及其双铑（I）配合物
Di-( m- m- m)terphenyl-Embedded Decaphyrin and Its Bis-Rh(I) Complex.
作者信息
Das Mainak, Adinarayana B, Murugavel M, Nayak Subhashree, Srinivasan A
机构信息
School of Chemical Sciences , National Institute of Science Education and Research (NISER), HBNI , Bhubaneswar 752050 , Odisha , India.
出版信息
Org Lett. 2019 Apr 19;21(8):2867-2871. doi: 10.1021/acs.orglett.9b00871. Epub 2019 Apr 8.
A new rectangular-shaped carbadecaphyrin was successfully synthesized by introducing a terphenylene unit ( m- m- m) in the macrocyclic core. The terphenylene moiety offers an open framework with multiple binding pockets to stabilize two Rh(I) ions in the core. The photophysical and structural studies reveal the non-aromatic character of the ligand and its bis-Rh(I) complex.
通过在大环核心引入一个对三联苯单元（间 - 间 - 间），成功合成了一种新型矩形咔哒十卟啉。对三联苯部分提供了一个具有多个结合口袋的开放框架，以稳定核心中的两个铑（I）离子。光物理和结构研究揭示了配体及其双铑（I）配合物的非芳香特性。
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