Influence of Combustion Modifiers on the Cure Kinetics of Glycidyl Azide Polymer Based Propellant-Evaluated through Rheo-Kinetic Approach.

To investigate the influence of combustion modifiers on the curing of glycidyl azide polymer spherical propellants (GAPSPs), the curing process of the GAPSPs was explored using an isothermal rheological measurement method. The parameters of cure kinetics were solved to further establish a kinetic model for the curing reaction of GAPSPs. The results showed that the curing process of GAPSPs under isothermal conditions conformed to the Kamal and LSK (Lu⁻Shim⁻Kim) models. The model data indicated significant agreement with the experimental data. The influence of four kinds of combustion performance modifiers on the curing process was explored and the results demonstrated that lead phthalate had a catalytic effect on the curing reaction of GAPSPs, whilst oxides of lead and copper, and copper adipate had no influence on the curing reaction.