Zhang Yunhe, Fang Jing, Li Jian, Guo Yanling, Wang Qingwen
College of Mechanical and Electrical Engineering, Northeast Forestry University, Harbin 150040, China.
College of Marterials and Energy, South China Agricultural University, Guangzhou 510642, China.
Polymers (Basel). 2017 Dec 18;9(12):728. doi: 10.3390/polym9120728.
Wood-plastic composites (WPCs) made by selective laser sintering (SLS) approach of 3D printing offer many advantages over single polymer materials, such as low cost, sustainability, and better sintering accuracy. However, WPCs made via SLS are too weak to have widespread applications. In order to increase the mechanical properties of WPCs, a novel type of WPCs containing 0, 0.05, 0.1 and 0.15 wt % carbon nanotubes (CNT), 14 wt % wood fibers, 86 wt % polyether sulfone (PES) was manufactured via SLS. The experimental results showed that the addition of small amount of CNTs can significantly increase the mechanical properties of the wood/PES composite material. The tensile strength, bending strength, and elasticity modulus were 76.3%, 227.9%, and 128.7% higher with 0.1 wt % CNTs than those without CNTs. The mechanical properties of specimens first increased and then decreased with the addition of CNTs. The SEM results of the specimens' fracture morphology indicate that the preferable bonding interfaces between wood flour grains and PES grains were achieved by adding CNTs to the composites. There are two reasons why the composites possessed superior mechanical properties: CNTs facilitate the laser sintering process of WPCs due to their thermal conductivities, and CNTs directly reinforce WPCs.
通过三维打印的选择性激光烧结(SLS)方法制造的木塑复合材料(WPC)比单一聚合物材料具有许多优势,如低成本、可持续性和更好的烧结精度。然而,通过SLS制造的WPC强度太弱,无法广泛应用。为了提高WPC的机械性能,通过SLS制造了一种新型的WPC,其包含0、0.05、0.1和0.15 wt%的碳纳米管(CNT)、14 wt%的木纤维、86 wt%的聚醚砜(PES)。实验结果表明,添加少量的CNT可以显著提高木材/PES复合材料的机械性能。添加0.1 wt% CNT时的拉伸强度、弯曲强度和弹性模量分别比不添加CNT时高76.3%、227.9%和128.7%。随着CNT的添加,试样的机械性能先增加后降低。试样断裂形态的扫描电子显微镜(SEM)结果表明,通过在复合材料中添加CNT,实现了木粉颗粒与PES颗粒之间较好的粘结界面。复合材料具有优异机械性能的原因有两个:由于CNT的热导率,它们促进了WPC的激光烧结过程,并且CNT直接增强了WPC。