• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过自由基悬浮聚合制备支化聚苯乙烯及其性能

Preparation and Properties of Branched Polystyrene through Radical Suspension Polymerization.

作者信息

Huang Wenyan, Gu Weikai, Yang Hongjun, Xue Xiaoqiang, Jiang Bibiao, Zhang Dongliang, Fang Jianbo, Chen Jianhai, Yang Yang, Guo Jinlong

机构信息

School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China.

出版信息

Polymers (Basel). 2017 Jan 6;9(1):14. doi: 10.3390/polym9010014.

DOI:10.3390/polym9010014
PMID:30970692
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6432501/
Abstract

Radical solvent-free suspension polymerization of styrene with 3-mercapto hexyl-methacrylate (MHM) as the branching monomer has been carried out using 2,2'-azobisisobutyronitrile (AIBN) as the initiator to prepare branched polymer beads of high purity. The molecular weight and branching structure of the polymers have been characterized by triple detection size exclusion chromatography (TD-SEC), proton nuclear magnetic resonance spectroscopy (¹H-NMR), and Fourier transform infrared spectroscopy (FTIR). The glass transition temperature and rheological properties have been measured by using differential scanning calorimetry (DSC) and rotational rheometry. At mole ratios of MHM to AIBN less than 1.0, gelation was successfully avoided and branched polystyrene beads were prepared in the absence of any solvent. Branched polystyrene has a relatively higher molecular weight and narrower polydispersity ( = 1,036,000 g·mol, / = 7.76) than those obtained in solution polymerization. Compared with their linear analogues, lower glass transition temperature and decreased chain entanglement were observed in the presently obtained branched polystyrene because of the effects of branching.

摘要

以2,2'-偶氮二异丁腈（AIBN）为引发剂，以3-巯基己基甲基丙烯酸酯（MHM）为支化单体，进行了苯乙烯的无溶剂自由基悬浮聚合，以制备高纯度的支化聚合物珠粒。通过三检测尺寸排阻色谱法（TD-SEC）、质子核磁共振光谱法（¹H-NMR）和傅里叶变换红外光谱法（FTIR）对聚合物的分子量和支化结构进行了表征。使用差示扫描量热法（DSC）和旋转流变仪测量了玻璃化转变温度和流变性能。在MHM与AIBN的摩尔比小于1.0时，成功避免了凝胶化，并且在没有任何溶剂的情况下制备了支化聚苯乙烯珠粒。与溶液聚合得到的产物相比，支化聚苯乙烯具有相对较高的分子量和较窄的多分散性（ = 1,036,000 g·mol， / = 7.76）。由于支化的影响，与它们的线性类似物相比，目前得到的支化聚苯乙烯具有较低的玻璃化转变温度和减少的链缠结。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/d6c5d2ba65d5/polymers-09-00014-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/40b7033577c2/polymers-09-00014-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/6b95518ccd77/polymers-09-00014-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/82d650e95446/polymers-09-00014-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/27381f275cd9/polymers-09-00014-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/17ceea971a46/polymers-09-00014-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/350276701ff8/polymers-09-00014-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/d6c5d2ba65d5/polymers-09-00014-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/40b7033577c2/polymers-09-00014-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/6b95518ccd77/polymers-09-00014-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/82d650e95446/polymers-09-00014-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/27381f275cd9/polymers-09-00014-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/17ceea971a46/polymers-09-00014-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/350276701ff8/polymers-09-00014-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5fc0/6432501/d6c5d2ba65d5/polymers-09-00014-g007.jpg

相似文献

1
Preparation and Properties of Branched Polystyrene through Radical Suspension Polymerization.通过自由基悬浮聚合制备支化聚苯乙烯及其性能
Polymers (Basel). 2017 Jan 6;9(1):14. doi: 10.3390/polym9010014.
2
On the formation of narrowly polydispersed PMMA by surface initiated polymerization (SIP) from AIBN-coated/intercalated clay nanoparticle platelets.关于通过表面引发聚合（SIP）由涂覆有偶氮二异丁腈/插层的粘土纳米颗粒片晶形成窄多分散性聚甲基丙烯酸甲酯。
Langmuir. 2005 Mar 15;21(6):2537-44. doi: 10.1021/la048126n.
3
Erratum: Preparation of Poly(pentafluorophenyl acrylate) Functionalized SiO2 Beads for Protein Purification.勘误：用于蛋白质纯化的聚（丙烯酸五氟苯酯）功能化二氧化硅微珠的制备
J Vis Exp. 2019 Apr 30(146). doi: 10.3791/6328.
4
In Situ Synthesis of Poly(butyl methacrylate) in Anodic Aluminum Oxide Nanoreactors by Radical Polymerization: A Comparative Kinetics Analysis by Differential Scanning Calorimetry and H-NMR.通过自由基聚合在阳极氧化铝纳米反应器中原位合成聚甲基丙烯酸丁酯：差示扫描量热法和氢核磁共振的比较动力学分析
Polymers (Basel). 2021 Feb 17;13(4):602. doi: 10.3390/polym13040602.
5
Poly(-isopropylacrylamide--2-((diethylamino)methyl)-4-formyl-6-methoxyphenyl acrylate) Environmental Functional Copolymers: Synthesis, Characterizations, and Grafting with Amino Acids.聚（异丙基丙烯酰胺-2-（二乙氨基）甲基-4-甲酰基-6-甲氧基苯基丙烯酰胺）环境功能共聚物：合成、表征和氨基酸接枝。
Biomolecules. 2018 Nov 6;8(4):138. doi: 10.3390/biom8040138.
6
Preparation of cassava starch grafted with polystyrene by suspension polymerization.悬浮聚合法制备木薯淀粉接枝聚苯乙烯。
Carbohydr Polym. 2008 Sep 5;73(4):647-55. doi: 10.1016/j.carbpol.2008.01.006. Epub 2008 Jan 16.
7
Chemical modification of chitin by grafting with polystyrene using ammonium persulfate initiator.用过硫酸铵引发剂通过接枝聚苯乙烯对甲壳素进行化学修饰。
Carbohydr Polym. 2013 Nov 6;98(2):1618-23. doi: 10.1016/j.carbpol.2013.07.054. Epub 2013 Jul 31.
8
Synthesis and characterisation of highly branched polyisoprene: exploiting the "Strathclyde route" in anionic polymerisation.高度支化聚异戊二烯的合成与表征：在阴离子聚合中利用“斯特拉斯克莱德路线”
RSC Adv. 2018 Mar 26;8(21):11684-11692. doi: 10.1039/c8ra00884a. eCollection 2018 Mar 21.
9
Synthesis of homo- and copolymer containing sulfonic acid via atom transfer radical polymerization.通过原子转移自由基聚合合成含磺酸的均聚物和共聚物。
Des Monomers Polym. 2022 Sep 19;25(1):261-270. doi: 10.1080/15685551.2022.2126092. eCollection 2022.
10
Synthesis of PAN with adjustable molecular weight and low polydispersity index (PDI) value via reverse atom transfer radical polymerization.通过反向原子转移自由基聚合合成具有可调分子量和低多分散指数（PDI）值的聚丙烯腈。
Des Monomers Polym. 2019 Oct 26;22(1):180-186. doi: 10.1080/15685551.2019.1678557. eCollection 2019.

引用本文的文献

1
Trends in 2017/2018: Polymer Synthesis.2017/2018年趋势：聚合物合成
Polymers (Basel). 2019 Dec 25;12(1):39. doi: 10.3390/polym12010039.

本文引用的文献

1
Quadrangular prism: a unique self-assembly from amphiphilic hyperbranched PMA-b-PAA.四棱柱：两亲性超支化聚甲基丙烯酸甲酯-聚丙烯酸的独特自组装体。
Macromol Rapid Commun. 2014 Feb;35(3):330-6. doi: 10.1002/marc.201300743. Epub 2013 Dec 6.
2
Controlled homopolymerization of multi-vinyl monomers: dendritic polymers synthesized via an optimized ATRA reaction.多乙烯基单体的可控均聚反应：通过优化 ATRA 反应合成的树枝状聚合物。
Chem Commun (Camb). 2013 Oct 3;49(86):10124-6. doi: 10.1039/c3cc44898c.
3
Controlled multi-vinyl monomer homopolymerization through vinyl oligomer combination as a universal approach to hyperbranched architectures.
通过乙烯基低聚物组合控制多乙烯基单体均聚合，作为一种通用方法制备超支化结构。
Nat Commun. 2013;4:1873. doi: 10.1038/ncomms2887.
4
New method to access hyperbranched polymers with uniform structure via one-pot polymerization of inimer in microemulsion.通过在微乳液中一锅聚合单体的方法，得到具有均匀结构的超支化聚合物的新方法。
J Am Chem Soc. 2012 Sep 26;134(38):15680-3. doi: 10.1021/ja307174h. Epub 2012 Sep 13.
5
Synthesis of chain end functionalized linear and branched polymers by radical polymerisation in the presence of a silyl enol.在硅烯醇存在下通过自由基聚合合成链端官能化的线性和支化聚合物。
Chem Commun (Camb). 2010 Aug 21;46(31):5767-9. doi: 10.1039/c0cc01705a. Epub 2010 Jul 9.
6
Hyperbranched and highly branched polymer architectures--synthetic strategies and major characterization aspects.超支化和高度支化聚合物结构——合成策略及主要表征方面
Chem Rev. 2009 Nov;109(11):5924-73. doi: 10.1021/cr900068q.
7
Self-condensing vinyl polymerization: an approach to dendritic materials.自缩合乙烯基聚合：树枝状材料的一种制备方法。
Science. 1995 Aug 25;269(5227):1080-3. doi: 10.1126/science.269.5227.1080.
8
Synthesis of branched poly(methyl methacrylate)s via controlled/living polymerisations exploiting ethylene glycol dimethacrylate as branching agent.利用乙二醇二甲基丙烯酸酯作为支化剂，通过可控/活性聚合反应合成支化聚甲基丙烯酸甲酯。
Chem Commun (Camb). 2004 May 7(9):1138-9. doi: 10.1039/b401709a. Epub 2004 Mar 25.