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超声辅助电泳沉积法制备的碳纳米管涂层对碳纤维及其复合材料界面性能的影响

Influence of Carbon Nanotube Coatings on Carbon Fiber by Ultrasonically Assisted Electrophoretic Deposition on Its Composite Interfacial Property.

作者信息

Jiang Jianjun, Xu Chumeng, Su Yang, Guo Qiang, Liu Fa, Deng Chao, Yao Xuming, Zhou Linchao

机构信息

Shaanxi Engineering Research Center for Digital Manufacturing Technology, Northwestern Polytechnical University, Xi'an 710072, China.

出版信息

Polymers (Basel). 2016 Aug 17;8(8):302. doi: 10.3390/polym8080302.

Abstract

Carbon nanotube (CNT) coatings were utilized to enhance the interfacial properties of carbon fiber (CF)/epoxy(EP) composites by ultrasonically assisted electrophoretic deposition (EPD). A characterization of the CF surface properties was done before and after coating (surface chemistry, surface morphologies, and surface energy). The result shows that oxygenated groups concentrations of the CF surfaces experienced significant increases from 12.11% to 24.78%. Moreover, the uniform and homogeneous CNT films were tightly attached on the surface of CF, and the surface wettability of CF is significant improved by enhanced surface free energy when introduced ultrasonic during the EPD process. In addition, the interlaminar shear strength (ILSS) and water absorption of CF/EP composite were measured. Scanning electron microscopy (SEM) revealed that the fracture mechanisms of the new interface layer formed by depositing CNTs on the CF surface contributed to the enhancement of the mechanical performance of the epoxy. This means that the efficient method to improve interfacial performance of composites has shown great commercial application potential.

摘要

利用碳纳米管(CNT)涂层通过超声辅助电泳沉积(EPD)来增强碳纤维(CF)/环氧树脂(EP)复合材料的界面性能。在涂层前后对CF的表面性能进行了表征(表面化学、表面形貌和表面能)。结果表明,CF表面的含氧基团浓度从12.11%显著增加到24.78%。此外,均匀且均质的CNT薄膜紧密附着在CF表面,并且在EPD过程中引入超声时,CF的表面润湿性通过提高表面自由能而得到显著改善。另外,测量了CF/EP复合材料的层间剪切强度(ILSS)和吸水率。扫描电子显微镜(SEM)显示,通过在CF表面沉积CNT形成的新界面层的断裂机制有助于提高环氧树脂的力学性能。这意味着这种改善复合材料界面性能的有效方法具有巨大的商业应用潜力。

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