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蜡包覆微晶纤维素增强环氧复合材料的表征

Characterization of Epoxy Composites Reinforced with Wax Encapsulated Microcrystalline Cellulose.

作者信息

Pan Yuanfeng, Pan Ying, Cheng Qingzheng, Liu Yi, Essien Charles, Via Brian, Wang Xiaoying, Sun Runcang, Taylor Steven

机构信息

Forest Products Development Center, School of Forestry and Wildlife Sciences, Auburn University, Auburn, AL 36849, USA.

State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.

出版信息

Polymers (Basel). 2016 Nov 30;8(12):415. doi: 10.3390/polym8120415.

Abstract

The effect of paraffin wax encapsulated microcrystalline cellulose (EMC) particles on the mechanical and physical properties of EMC/epoxy composites were investigated. It was demonstrated that the compatibility between cellulose and epoxy resin could be maintained due to partial encapsulation resulting in an improvement in epoxy composite mechanical properties. This work was unique because it was possible to improve the physical and mechanical properties of the EMC/epoxy composites while encapsulating the microcrystalline cellulose (MCC) for a more homogeneous dispersion. The addition of EMC could increase the stiffness of epoxy composites, especially when the composites were wet. The 1% EMC loading with a 1:2 ratio of wax:MCC demonstrated the best reinforcement for both dry and wet properties. The decomposition temperature of epoxy was preserved up to a 5% EMC loading and for different wax:MCC ratios. An increase in wax encapsulated cellulose loading did increase water absorption but overall this absorption was still low (<1%) for all composites.

摘要

研究了石蜡包覆微晶纤维素(EMC)颗粒对EMC/环氧树脂复合材料力学和物理性能的影响。结果表明,由于部分包覆作用,纤维素与环氧树脂之间的相容性得以保持,从而使环氧树脂复合材料的力学性能得到改善。这项工作具有独特性,因为在将微晶纤维素(MCC)包覆以实现更均匀分散的同时,还能够改善EMC/环氧树脂复合材料的物理和力学性能。添加EMC可以提高环氧树脂复合材料的刚度,尤其是当复合材料处于潮湿状态时。蜡与MCC比例为1:2的1%EMC负载量对干、湿性能均表现出最佳增强效果。在EMC负载量高达5%且蜡与MCC比例不同的情况下,环氧树脂的分解温度得以保持。蜡包覆纤维素负载量的增加确实会提高吸水率,但总体而言,所有复合材料的吸水率仍然较低(<1%)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bfad/6432487/3ac538c15dd0/polymers-08-00415-g001.jpg

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