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聚合物转位动力学:一篇简短综述及弱驱动机制介绍

Dynamics of Polymer Translocation: A Short Review with an Introduction of Weakly-Driven Regime.

作者信息

Sakaue Takahiro

机构信息

Department of Physics, Kyushu University, Fukuoka 819-0395, Japan.

Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency, Honcho Kawaguchi, Saitama 332-0012, Japan.

出版信息

Polymers (Basel). 2016 Dec 7;8(12):424. doi: 10.3390/polym8120424.

DOI:10.3390/polym8120424
PMID:30974699
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6432367/
Abstract

As emphasized in a recent review (by V.V. Palyulin, T. Ala-Nissila, R. Metzler), theoretical understanding of the unbiased polymer translocation lags behind that of the (strongly) driven translocation. Here, we suggest the introduction of a , as described by the linear response theory to the unbiased regime, which is followed by the strongly-driven regime beyond the onset of nonlinear response. This provides a concise crossover scenario, bridging the unbiased to strongly-driven regimes.

摘要

正如最近一篇综述(由V.V. 帕柳林、T. 阿拉 - 尼斯利拉、R. 梅茨勒撰写)所强调的,对无偏聚合物转位的理论理解落后于(强)驱动转位的理论理解。在此,我们建议引入一种 ,如线性响应理论所描述的,用于无偏状态,随后是超出非线性响应起始点的强驱动状态。这提供了一个简洁的交叉情景,将无偏状态与强驱动状态联系起来。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/761c/6432367/ae8d7edb6994/polymers-08-00424-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/761c/6432367/778266cdbe58/polymers-08-00424-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/761c/6432367/a4fe8bc7bd23/polymers-08-00424-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/761c/6432367/ae8d7edb6994/polymers-08-00424-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/761c/6432367/778266cdbe58/polymers-08-00424-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/761c/6432367/a4fe8bc7bd23/polymers-08-00424-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/761c/6432367/ae8d7edb6994/polymers-08-00424-g003.jpg

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本文引用的文献

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2
Iso-flux tension propagation theory of driven polymer translocation: the role of initial configurations.驱动聚合物转位的等通量张力传播理论:初始构型的作用。
J Chem Phys. 2014 Dec 7;141(21):214907. doi: 10.1063/1.4903176.
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Polymer translocation: the first two decades and the recent diversification.聚合物转位:头二十年及近期的多样化发展
带电聚合物在单价和二价盐溶液中通过纳米孔的转位:一项探索整个驱动力范围的标度研究
Polymers (Basel). 2018 Nov 6;10(11):1229. doi: 10.3390/polym10111229.
4
Polymer Translocation Across a Corrugated Channel: Fick⁻Jacobs Approximation Extended Beyond the Mean First-Passage Time.聚合物通过波纹通道的转运:超越平均首次通过时间的菲克-雅各布斯近似法
Polymers (Basel). 2019 Feb 2;11(2):251. doi: 10.3390/polym11020251.
5
Theoretical Modeling of Polymer Translocation: From the Electrohydrodynamics of Short Polymers to the Fluctuating Long Polymers.聚合物转位的理论建模:从短聚合物的电流体动力学到波动的长聚合物
Polymers (Basel). 2019 Jan 11;11(1):118. doi: 10.3390/polym11010118.
Soft Matter. 2014 Dec 7;10(45):9016-37. doi: 10.1039/c4sm01819b. Epub 2014 Oct 10.
4
Evaluating the applicability of the Fokker-Planck equation in polymer translocation: a Brownian dynamics study.评估福克-普朗克方程在聚合物转位中的适用性:一项布朗动力学研究。
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