Abellán Gonzalo, Amo-Ochoa Pilar, Fierro José Luis G, Ribera Antonio, Coronado Eugenio, Zamora Félix
Instituto de Ciencia Molecular, Universidad de Valencia, Catedrático José Beltrán 2, Paterna, Valencia 46980, Spain.
Department of Chemistry and Pharmacy and Institute of Advanced Materials and Processes (ZMP), University Erlangen-Nuremberg, Henkestr. 42, Erlangen 91054 and Dr.-Mack Str. 81, Fürth 90762, Germany.
Polymers (Basel). 2015 Dec 29;8(1):5. doi: 10.3390/polym8010005.
The preparation and characterization of a novel hybrid material based on the combination of a 2D-layered double hydroxide (LDH) nanosheets and a 1D-coordination polymer (1D-CP) has been achieved through a simple mixture of suspensions of both building blocks via an exfoliation/restacking approach. The hybrid material has been thoroughly characterized demonstrating that the 1D-CP moieties are intercalated as well as adsorbed on the surface of the LDH, giving rise to a layered assembly with the coexistence of the functionalities of their initial constituents. This hybrid represents the first example of the assembly of 1D/2D nanomaterials combining LDH with CP and opens the door for a plethora of different functional hybrid systems.
通过二维层状双氢氧化物（LDH）纳米片和一维配位聚合物（1D-CP）这两种结构单元的悬浮液经剥离/再堆叠方法简单混合，制备并表征了一种新型杂化材料。该杂化材料已得到充分表征，结果表明一维配位聚合物部分既插层于层状双氢氧化物表面，又吸附在其表面，形成了一种层状组装体，兼具初始组分的功能。这种杂化材料是层状双氢氧化物与配位聚合物结合的一维/二维纳米材料组装的首个实例，为众多不同的功能杂化体系打开了大门。
