Departamento de Química Inorgánica, Universidad Autónoma de Madrid, E-28049 Madrid, Spain.
Adv Mater. 2013 Apr 18;25(15):2141-6. doi: 10.1002/adma.201204676. Epub 2013 Jan 23.
A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties.
只有通过溶剂辅助相互作用才能使配位聚合物完全剥离。软层离过程源于起始材料的结构，该结构具有层状结构，层与层之间的相互作用较弱，并且有空腔，可以以非选择性的方式定位几种溶剂。这些结果代表了在制备具有定制物理化学性质的结构设计的单分子厚二维材料方面迈出了重要的一步。
