Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92023-0358, USA.
Chem Commun (Camb). 2019 May 10;55(37):5367-5370. doi: 10.1039/c9cc02252j. Epub 2019 Apr 17.
A library of 26 mixed ligand UiO-66 analogs was synthesized, characterized, and screened for catalytic degradation of the chemical warfare agent (CWA) simulant dimethyl 4-nitrophenylphosphate (DMNP). The MOFs were screened and compared to physical mixtures of the same single component MOFs. Several of the MOFs display higher catalytic activity than the parent UiO-66 and other single ligand UiO-66 analogues.
合成了 26 种混合配体 UiO-66 类似物库，并对其进行了表征和筛选，以催化降解化学战剂（CWA）模拟物二甲基 4-硝基苯膦酸酯（DMNP）。对 MOFs 进行了筛选，并与相同单一组分 MOFs 的物理混合物进行了比较。几种 MOFs 的催化活性高于母体 UiO-66 和其他单配体 UiO-66 类似物。
