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用于高性能溶液处理混合白色有机发光二极管的高效热激活延迟荧光蓝色主体的设计

Design of efficient thermally activated delayed fluorescence blue host for high performance solution-processed hybrid white organic light emitting diodes.

作者信息

Ban Xinxin, Chen Feng, Liu Yan, Pan Jie, Zhu Aiyun, Jiang Wei, Sun Yueming

机构信息

Jiangsu Key Laboratory of Function Control Technology for Advanced Materials , School of Chemical Engineering , Huaihai Institute of Technology , Lianyungang , Jiangsu 222005 , P. R. China . Email:

School of Chemistry and Chemical Engineering , Southeast University , Nanjing , Jiangsu 211189 , P. R. China . Email:

出版信息

Chem Sci. 2019 Jan 15;10(10):3054-3064. doi: 10.1039/c8sc05456h. eCollection 2019 Mar 14.

Abstract

Developing a solution-processible blue thermally activated delayed fluorescence (TADF) emitter for hybrid white organic light emitting diodes (WOLEDs) is still a challenge. In this work, two TADF blue emitters are designed and synthesized to explore a common strategy to qualify the small molecular TADF material as a solution-processible blue host. Systematic studies find that the molecular encapsulation by introducing unconjugated carbazoles as steric shields not only keeps the intrinsic TADF feature unchanged, but also effectively suppress the intermolecular interaction induced exciton quenching, which makes the material more efficient for solution-processing. The optimized solution-processed hybrid WOLEDs based on the encapsulated TADF blue host realized a highly efficient device performance with a maximum current efficiency (CE), power efficiency (PE) and external quantum efficiency (EQE) of 45.6 cd A, 40.9 lm W and 17.0%, respectively, which are three times higher in device efficiency and twenty times higher in device lifetime than the corresponding device with an unencapsulated TADF blue host. Furthermore, the obtained device exhibits a high electroluminescence (EL) above 20 000 cd m and a stable EL spectrum with nearly unchanged Commission International de L'Eclairage (CIE) coordinate at a wide range of applied voltages. These results clearly demonstrate that the molecular encapsulation of the TADF blue host is a superior and promising strategy to achieve high performance and color stable solution-processed hybrid WOLEDs.

摘要

为混合白光有机发光二极管(WOLED)开发一种可溶液加工的蓝色热激活延迟荧光(TADF)发射体仍然是一项挑战。在这项工作中,设计并合成了两种TADF蓝色发射体,以探索一种通用策略,使小分子TADF材料成为可溶液加工的蓝色主体。系统研究发现,通过引入非共轭咔唑作为空间屏蔽进行分子封装,不仅能保持固有的TADF特性不变,还能有效抑制分子间相互作用引起的激子猝灭,这使得该材料在溶液加工方面更高效。基于封装后的TADF蓝色主体优化的可溶液加工混合WOLED实现了高效的器件性能,最大电流效率(CE)、功率效率(PE)和外量子效率(EQE)分别为45.6 cd/A、40.9 lm/W和17.0%,其器件效率是使用未封装TADF蓝色主体的相应器件的三倍,器件寿命则高出二十倍。此外,所制备的器件在高于20000 cd/m²的亮度下表现出高电致发光(EL),并且在很宽的施加电压范围内具有稳定的EL光谱,国际照明委员会(CIE)坐标几乎不变。这些结果清楚地表明,TADF蓝色主体的分子封装是实现高性能和颜色稳定的可溶液加工混合WOLED的一种卓越且有前景的策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27bf/6428138/04b8a019f50a/c8sc05456h-s1.jpg

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