Matsuno Jobu, Fujioka Jun, Okuda Tetsuji, Ueno Kazunori, Mizokawa Takashi, Katsufuji Takuro
Department of Physics, Osaka University, Osaka, Japan.
Center for Emergent Matter Science (CEMS), RIKEN, Saitama, Japan.
Sci Technol Adv Mater. 2018 Nov 26;19(1):899-908. doi: 10.1080/14686996.2018.1529524. eCollection 2018.
We review recent advances in strongly correlated oxides as thermoelectric materials in pursuit of energy harvesting. We discuss two topics: one is the enhancement of the ordinary thermoelectric properties by controlling orbital degrees of freedom and orbital fluctuation not only in bulk but also at the interface of correlated oxides. The other topic is the use of new phenomena driven by spin-orbit coupling (SOC) of materials. In 5 electron oxides, we show some SOC-related transport phenomena, which potentially contribute to energy harvesting. We outline the current status and a future perspective of oxides as thermoelectric materials.
我们回顾了强关联氧化物作为热电材料在能量收集方面的最新进展。我们讨论两个主题:一是通过控制轨道自由度和轨道涨落来增强普通热电性能,这不仅适用于块体材料,也适用于关联氧化物的界面。另一个主题是利用材料的自旋轨道耦合(SOC)驱动的新现象。在五价电子氧化物中,我们展示了一些与SOC相关的输运现象,这些现象可能有助于能量收集。我们概述了氧化物作为热电材料的现状和未来前景。