Institute of Organic Chemistry Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
Molecules. 2019 Apr 18;24(8):1533. doi: 10.3390/molecules24081533.
Heterocycles are important class of structures, which occupy a major space in the domain of natural and bioactive compounds. For this reason, development of new synthetic strategies for their controllable synthesis became of special interests. The development of novel photoredox systems with wide-range application in organic synthesis is particularly interesting. Organic dyes have been widely applied as photoredox catalysts in organic synthesis. Their low costs compared to the typical photocatalysts based on transition metals make them an excellent alternative. This review describes proceedings since 2015 in the area of application of metal-free, visible-light-mediated catalysis for assembling various heterocyclic scaffolds containing five- and six-membered rings bearing nitrogen and oxygen heteroatoms.
杂环是一类重要的结构,在天然和生物活性化合物领域占据重要地位。因此,开发可控合成它们的新合成策略引起了特别的关注。新型光氧化还原体系的发展在有机合成中具有广泛的应用,特别有趣。有机染料已广泛应用于有机合成中的光氧化还原催化剂。与基于过渡金属的典型光催化剂相比,它们的成本低,因此是一种极好的替代品。本综述描述了自 2015 年以来在应用无金属、可见光介导催化合成含氮和氧杂原子的五元环和六元环各种杂环骨架方面的进展。