双金属催化的级联反应通过原位生成2-叠氮基丙烯高效合成N-异丙烯基-1,2,3-三唑
Bimetal-Catalyzed Cascade Reaction for Efficient Synthesis of N-Isopropenyl 1,2,3-Triazoles via In-Situ Generated 2-Azidopropenes.
作者信息
Liu Zhenhua, Hao Wenjing, Liu Zhixian, Gao Wen, Zhang Zhihai, Zhang Yanan, Li Xiang, Tong Lili, Tang Bo
机构信息
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan, 250014, P. R. China.
出版信息
Chem Asian J. 2019 Jun 14;14(12):2149-2154. doi: 10.1002/asia.201900402. Epub 2019 May 21.
A bimetal-catalyzed cascade reaction for the synthesis of N-isopropenyl 1,2,3-triazoles in high yield is reported. This reaction involves the generation of 2-azidopropenes in situ by C(sp )-OAr bond cleavage for click reaction and features a broad substrate scope, good functional group tolerance and readily available substrates.
报道了一种双金属催化的级联反应，用于高产率合成N-异丙烯基-1,2,3-三唑。该反应涉及通过C(sp)-OAr键裂解原位生成2-叠氮基丙烯用于点击反应，具有底物范围广、官能团耐受性好和底物易于获得的特点。
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