N-氯代丁二酰亚胺（NCS）-N,N-二甲基甲酰胺（DMF），一种用于将苄醇氧化为醛和酮的试剂。
N-Chlorosuccinimide (NCS)-N,N-dimethylformamide (DMF), a reagent for the oxidation of benzylic alcohols to aldehydes and ketones.
机构信息
Organic Chemistry Research Centre, Department of Chemistry, K.R.T. Arts, B.H. Commerce and A.M. Science College, Gangapur Road, Nashik, MS, 422 002, India.
出版信息
Mol Divers. 2020 May;24(2):437-442. doi: 10.1007/s11030-019-09954-3. Epub 2019 May 2.
PMID:31049787
Abstract
The oxidation of benzylic alcohol to corresponding aldehyde and ketone using N-chlorosuccinimide (NCS)-N,N-dimethylformamide (DMF) has been described. This method gives easy access to the corresponding carbonyl compounds under metal-free conditions, without the use of corrosive reagent at ambient temperature in good yield.
摘要
已描述了使用 N-氯代丁二酰亚胺 (NCS)-N,N-二甲基甲酰胺 (DMF) 将苄醇氧化为相应的醛和酮。该方法在无金属条件下，在环境温度下使用腐蚀性试剂，以良好的收率轻松获得相应的羰基化合物。
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