Hämmerling Sebastian, Thiele Günther, Steinhauer Simon, Beckers Helmut, Müller Carsten, Riedel Sebastian
Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstr.34/36, 14195, Berlin, Germany.
Angew Chem Int Ed Engl. 2019 Jul 15;58(29):9807-9810. doi: 10.1002/anie.201904007. Epub 2019 Jun 17.
A new chloronium-containing salt, [Me Cl][Al(OTeF ) ], was synthesized on multigram scale by means of a simple one-pot procedure. The isolated product can be handled at room temperature and used as a strong electrophilic methylation agent. This is demonstrated by the methylation of the very weak bases P(CF ) , PF , MeI, and MeBr.
通过一种简单的一锅法以多克规模合成了一种新的含氯鎓盐[Me Cl][Al(OTeF ) ]。分离出的产物在室温下即可处理，并用作强亲电甲基化试剂。这通过极弱碱P(CF ) 、PF 、MeI和MeBr的甲基化得以证明。
