Namirembe Sheila, Morken James P
Department of Chemistry, Boston College, Chestnut Hill, MA 02467, USA.
Chem Soc Rev. 2019 Jul 1;48(13):3464-3474. doi: 10.1039/c9cs00180h.
This tutorial review describes recent developments in catalytic reaction design that involve catalyst-promoted 1,2-metalate shifts as a critical part of the reaction mechanism. Issues pertaining to catalysis, stereoselectivity, and reaction mechanism are discussed.
本教程综述描述了催化反应设计的最新进展,其中涉及催化剂促进的1,2-金属酸酯迁移作为反应机理的关键部分。讨论了与催化、立体选择性和反应机理相关的问题。