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一种多价混合金属策略，用于基于单铜离子桥连簇的硫属化物开放式框架，用于灵敏的非酶葡萄糖检测。

A multivalent mixed-metal strategy for single-Cu-ion-bridged cluster-based chalcogenide open frameworks for sensitive nonenzymatic detection of glucose.

机构信息

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China.

出版信息

Chem Commun (Camb). 2019 May 30;55(45):6357-6360. doi: 10.1039/c9cc02905b.

DOI:10.1039/c9cc02905b
PMID:31065633
Abstract

Here we report two new metal-chalcogenide open frameworks (MCOFs) with large-sized supertetrahedral clusters bridged by an accessible single-cuprous ion via a multivalent mixed-metal strategy. Such Cu-rich semiconductor MCOFs have been investigated for the first time for nonenzymatic detection of glucose, and display good sensitivity and stability.

摘要

在这里，我们报道了两个新的金属-硫属化物开放骨架（MCOFs），它们通过多价混合金属策略，由可接近的单一铜离子桥接大尺寸超四面体簇。首次研究了这种富铜半导体 MCOFs 对葡萄糖的非酶检测，表现出良好的灵敏度和稳定性。

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