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测量消化液中液体部分的有机肥料特性。

Measuring the organic amendment properties of the liquid fraction of digestate.

机构信息

Gruppo Ricicla Lab., Dipartimento di Scienze Agrarie e Ambientali, Produzione, Territorio, Agroenergia, Università degli Studi di Milano, Via Celoria 2, 20133 Milan, Italy.

Gruppo Ricicla Lab., Dipartimento di Scienze Agrarie e Ambientali, Produzione, Territorio, Agroenergia, Università degli Studi di Milano, Via Celoria 2, 20133 Milan, Italy.

出版信息

Waste Manag. 2019 Apr 1;88:21-27. doi: 10.1016/j.wasman.2019.03.024. Epub 2019 Mar 19.

Abstract

The liquid fraction (LF) of digestate has usually been proposed as a substitute for mineral fertilizers because of the presence of high N content, above all in easily available form (ammonia). The LF was reported to contain about 66% of dry matter from the digestate. This study reports the characterization of the organic carbon (OC) contained in the LF of digestates obtained from full scale plants by screw-press solid/liquid separation, to find out about their organic amendment properties. Results indicate that LF contains stable OC because of the concentration during anaerobic digestion of recalcitrant molecules, and that its biological stability, measured by oxygen uptake rate, was similar to that of compost, i.e. 40 ± 15 mg O g DM 20 h and 41.1 ± 5.1 mg O g DM 20 h. C NMR indicated that LFs were similar each other and were constituted of recalcitrant Alkyl-C (34.82 ± 5.28% OC) derived from plant and fecal material, Aromatic-C (11.10 ± 2.2% OC) derived from lignin-like structures and O/N-alkyl (44.91 ± 4.87% OC) derived from cellulose/hemicelluloses and protein material. A simple simulation of the real C dosed by using LF as N-fertilizers indicated that amendment properties cannot be ignored. All these results seem to indicate good amendment properties for LFs, contrary to the common opinion.

摘要

消化液的液体部分(LF)通常被提议作为矿物肥料的替代品,因为它含有高含量的氮,尤其是在易生物利用的形式(氨)中。LF 被报道含有约 66%的干物质来自消化物。本研究报告了通过螺旋压榨固/液分离从全规模工厂获得的消化物 LF 中有机碳(OC)的特性,以了解其有机改良剂的性质。结果表明,LF 中含有稳定的 OC,因为在厌氧消化过程中,难降解分子的浓度增加,其生物稳定性(以耗氧速率衡量)与堆肥相似,即 40±15mg O g DM 20 h 和 41.1±5.1mg O g DM 20 h。13C NMR 表明,LF 彼此相似,由植物和粪便材料来源的难降解烷基-C(34.82±5.28%OC)、木质素样结构来源的芳基-C(11.10±2.2%OC)和纤维素/半纤维素和蛋白质材料来源的 O/N-烷基-C(44.91±4.87%OC)组成。使用 LF 作为氮肥实际施碳的简单模拟表明,改良剂的性质不能被忽视。所有这些结果似乎表明 LF 具有良好的改良剂性质,这与普遍看法相反。

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