通过硼烯插入硼二硫属环戊二烯合成不对称硼酯和硼酯杂环。
Synthesis of unsymmetrical BE and BE heterocycles by borylene insertion into boradichalcogeniranes.
作者信息
Liu Siyuan, Légaré Marc-André, Hofmann Alexander, Rempel Anna, Hagspiel Stephan, Braunschweig Holger
机构信息
Institut für Anorganische Chemie , Julius-Maximilians-Universität Würzburg , Am Hubland , 97074 Würzburg , Germany . Email:
Institute for Sustainable Chemistry & Catalysis with Boron , Julius-Maximilians-Universität Würzburg , Am Hubland , 97074 Würzburg , Germany.
出版信息
Chem Sci. 2019 Mar 19;10(17):4662-4666. doi: 10.1039/c9sc00657e. eCollection 2019 May 7.
We report the selective insertion of a range of borylene fragments into the E-E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings.
我们报道了一系列硼烯片段选择性插入环状二硼硫属化合物的E-E键（E = S、Se、Te）的反应。该方法为合成各种对称和不对称的四元环及五元环提供了简便途径。
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