Departamento de Edafoloxía e Química Agrícola, Facultade de Farmacia, Universidade de Santiago de Compostela, Praza Seminario de Estudos Galegos s/n, 15782, Santiago de Compostela, Spain.
Chemical Engineering Department, Barcelona East School of Engineering (EEBE); Barcelona Research Center for Multiscale Science and Engineering, Polytechnic University of Catalonia (UPC)-Barcelona TECH, Campus Diagonal-Besòs, 08930, Barcelona, Spain.
Environ Sci Pollut Res Int. 2019 Jul;26(21):21085-21097. doi: 10.1007/s11356-019-05462-x. Epub 2019 May 24.
The use of composts and vermicomposts as adsorbents is an important topic of study in the field of environmental remediation. These materials are rich in organic matter and have functional groups that can interact with organic and inorganic compounds. They also contain microorganisms that can promote biodegradation of organic substances. Composts that cannot be used for agronomic purposes (owing to e.g. low nutrient levels or phytotoxicity) may be valuable for soil remediation or pollutant removal. In this review, we discuss papers on this topic, with the objective of drawing attention to the potential use of composts/vermicomposts and to recommend further investigation on this subject. Few published studies have investigated the use of composts/vermicomposts to remove dyes and other coloured compounds. However, preliminary results show that these materials are potentially good adsorbents, at least comparable to other low-cost adsorbents, and that, in general, basic dyes are more efficiently removed than direct, reactive or acid dyes. The results of the works reviewed also show that dye removal takes place by adsorption mechanisms, in most studies following a Langmuir model, and that the kinetics of removal are fast and follow a pseudo-second order model. However, there remain several uncertainties regarding this application. For example, very few dyes have been studied so far, and little is known about the influence of the properties of composts/vermicomposts on the dye removal process. Moreover, the possible use of compost/vermicompost to enhance biodegradation processes has not been explored. All these questions should be addressed in future research.
使用堆肥和蚯蚓粪作为吸附剂是环境修复领域的一个重要研究课题。这些材料富含有机物,具有可以与有机和无机化合物相互作用的官能团。它们还含有可以促进有机物质生物降解的微生物。不能用于农业目的的堆肥(例如由于养分水平低或植物毒性)可能对土壤修复或污染物去除具有价值。在这篇综述中,我们讨论了关于这个主题的论文,目的是引起人们对堆肥/蚯蚓粪的潜在用途的关注,并建议对此主题进行进一步研究。很少有发表的研究调查了堆肥/蚯蚓粪在去除染料和其他有色化合物方面的用途。然而,初步结果表明,这些材料是潜在的良好吸附剂,至少与其他低成本吸附剂相当,并且通常,碱性染料比直接、反应性或酸性染料更有效地去除。综述工作的结果还表明,染料的去除是通过吸附机制发生的,在大多数研究中遵循朗缪尔模型,并且去除的动力学很快且遵循伪二阶模型。然而,关于这种应用仍然存在一些不确定性。例如,到目前为止,研究的染料很少,对堆肥/蚯蚓粪的性质对染料去除过程的影响知之甚少。此外,堆肥/蚯蚓粪的可能用途来增强生物降解过程尚未得到探索。所有这些问题都应在未来的研究中得到解决。