Highly Uniform and Porous Polyurea Microspheres: Clean and Easy Preparation by Interface Polymerization, Palladium Incorporation, and High Catalytic Performance for Dye Degradation.

Owing to their high specific surface area and low density, porous polymer materials are of great importance in a vast variety of applications, particularly as supports for enzymes and transition metals. Herein, highly uniform and porous polyurea microspheres (PPM), with size between 200 and 500 μm, are prepared by interfacial polymerization of toluene diisocyanate (TDI) in water through a simple microfluidic device composed of two tube lines, in one of which TDI is flowing and merged to the other with flowing aqueous phase, generating therefore TDI droplets at merging. The polymerization starts in the tube while flowing to the reactor and completed therein. This is a simple, easy and effective process for preparation of uniform PPM. Results demonstrate that the presence of polyvinyl alcohol in the aqueous flow is necessary to obtain uniform PPM. The size of PPM is readily adjustable by changing the polymerization conditions. In addition, palladium is incorporated in PPM to get the composite microspheres Pd@PPM, which are used as catalyst in degradation of methylene blue and rhodamine B. High performance and good reusability are demonstrated. Monodispersity, efficient dye degradation, easy recovery, and remarkable reusability make Pd@PPM a promising catalyst for dye degradation.