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生物相容的聚乳酸增强镍砷酸盐复合材料:电化学导电性、机械稳定性和细胞活力研究。

Biocompatible polylactic acid-reinforced nickel-arsenate composite: Studies of electrochemical conductivity, mechanical stability, and cell viability.

机构信息

Surfactants Research Chair, Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia.

Environmental Materials Division, CSIR-National Environmental Engineering Research Institute (CSIR-NEERI), Nehru Marg, Nagpur 440020, India.

出版信息

Mater Sci Eng C Mater Biol Appl. 2019 Sep;102:142-149. doi: 10.1016/j.msec.2019.04.046. Epub 2019 Apr 16.

Abstract

In continuation to our earlier work on nickel (Ni)-arsenate (As) composite, the current work deals with the electrical conductivity and mechanical resistivity of the same composite by means of its further reinforcement with the polylactic acid (PLA) polymer. For the PLA-Ni-As composite, we understand from the electrochemical studies that the conductivity is strongly influenced by the temperature and due to the presence of external electrolyte. The DC electrical conductivity approach used for the temperature dependency provided the information that the conductivity falls in the semiconductor zone ranging at 10 S cm, thereby indicating that it followed the Arrhenius equation. In addition, we found in terms of the mechanical properties that the PLA-Ni-As composite outperformed the plain, untreated Ni-As composite by reducing the activation energy. For the mechanical resistivity studies we found that the 25% PLA-loaded Ni-As material significantly improved the tensile strength and modulus, elongation at break %, impact properties and also the flexural strength and modulus as against the plain and other combinations due to enhanced interfacial interactions. The cell viability and proliferations studies tested against two different cell lines provided the information that the presence of polymer reduces the toxic response of arsenic material. From the cumulative analysis therefore, we indicate that the PLA-Ni-As composite can be a potential candidate to find its uses in the electrochemical and solar cells, in addition to automotive and aerospace industry.

摘要

继我们之前对镍(Ni)-砷酸盐(As)复合材料的研究之后,目前的工作通过进一步用聚乳酸(PLA)聚合物增强相同的复合材料来研究其电导率和机械电阻率。对于 PLA-Ni-As 复合材料,我们从电化学研究中了解到,导电性受温度和外部电解质的强烈影响。用于温度相关性的直流电导率方法提供的信息表明,电导率落在半导体区域内为 10 S cm,这表明它遵循阿累尼乌斯方程。此外,我们发现就机械性能而言,PLA-Ni-As 复合材料通过降低活化能优于未处理的纯 Ni-As 复合材料。对于机械电阻率研究,我们发现 25%负载 PLA 的 Ni-As 材料由于增强了界面相互作用,显著提高了拉伸强度和模量、断裂伸长率 %、冲击性能以及弯曲强度和模量。针对两种不同细胞系的细胞活力和增殖研究提供的信息表明,聚合物的存在降低了砷材料的毒性反应。因此,从累积分析来看,我们指出 PLA-Ni-As 复合材料可以成为电化学和太阳能电池以及汽车和航空航天工业的潜在候选材料。

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