Hebei and China Geological Survey Key Laboratory of Groundwater Remediation, Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Shijiazhuang 050061, China.
Int J Environ Res Public Health. 2019 May 30;16(11):1914. doi: 10.3390/ijerph16111914.
As the main anion of groundwater, the content of sulfate affects the drinking water safety and ecological security directly. In recent years, with the acceleration of industrialization and urbanization development, the problem of sulfate pollution in water environments is becoming more and more serious. It is critical to effectively identify the sulfate sources of water environment to ensure human health and the benign evolution of water environment. Due to its "fingerprints" feature, the sulfur and oxygen isotopes of SO have been widely used to identify sources of sulfate contamination in water environment. However, research advances in tracing sulfate contamination sources of water environment by using stable isotopes are rarely reported. This paper reviewed the research advances of sulfate isotope technology domestically and abroad, which was used to trace the sources of sulfate pollution in water environment, compared different pre-treatment methods for analyzing the δS and δO of sulfate, and compiled the ranges of typical values of δS and δO from different potential sources of sulfate contamination. In this review, the limitation of the technique in traceability of sulfate pollution was also discussed, and the future traceability techniques of sulfate pollution were prospected.
作为地下水的主要阴离子,硫酸盐的含量直接影响饮用水安全和生态安全。近年来,随着工业化和城市化进程的加速,水环境中硫酸盐污染问题日益严重。有效识别水环境中硫酸盐的来源对于保障人类健康和水环境的良性演化至关重要。由于其“指纹”特征,SO 的硫氧同位素已被广泛用于识别水环境中硫酸盐污染的来源。然而,利用稳定同位素追踪水环境中硫酸盐污染来源的研究进展却鲜有报道。本文综述了国内外硫酸盐同位素技术在追踪水环境中硫酸盐污染来源方面的研究进展,比较了分析硫酸盐 δS 和 δO 的不同预处理方法,并编制了不同潜在硫酸盐污染源的典型 δS 和 δO 值范围。本文还讨论了该技术在硫酸盐污染溯源中的局限性,并对未来的硫酸盐污染溯源技术进行了展望。