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采用电凝聚法和化学凝聚法处理明胶生产厂废水的对比研究。

A comparative study on the treatment of gelatin production plant wastewater using electrocoagulation and chemical coagulation.

作者信息

Arturi Tatiana S, Seijas Carlos J, Bianchi Gustavo L

机构信息

Energy and Environmental Innovation Group, Malvinas Institute, Faculty of Engineering, National University of La Plata, Diagonal 80 No 372, La Plata, Buenos Aires, 1900, Argentina.

出版信息

Heliyon. 2019 May 29;5(5):e01738. doi: 10.1016/j.heliyon.2019.e01738. eCollection 2019 May.

Abstract

Effluents from gelatin production plants are highly complex and difficult to treat by conventional methods. The Electrocoagulation (EC) technique was evaluated to treat effluents that contain a heavy load of Chemical Oxygen Demand (COD) and a large quantity of suspended solids. This paper presents results of laboratory scale studies that compare the performance of Chemical Coagulation (CC) with aluminum salts and EC with aluminum electrodes. The heavy organic load and suspended solids in this kind of wastewater lead to low performance in the secondary treatment. SEM-EDS were used to analyze the sludge formed in the EC process and the removal mechanism of pollutants from the wastewater. The structure and composition of the precipitates at different operation conditions, such as pH, show that EC has increased efficiency of COD removal, compared to CC with the same dose of aluminum (Al) as coagulant. The efficiency of COD removal was 73.6% with EC and 55.6% with CC. The in-situ formation of zeolites in the EC process explains the high efficiency of this treatment compared to the CC process. The zeolite formation during the EC process in the wastewater of the gelatin production plant has not been reported until now.

摘要

明胶生产厂的废水成分高度复杂,难以用传统方法处理。对电凝聚(EC)技术进行了评估,以处理含有高化学需氧量(COD)和大量悬浮固体的废水。本文介绍了实验室规模研究的结果,该研究比较了用铝盐进行化学凝聚(CC)和用铝电极进行电凝聚(EC)的性能。这类废水中的高有机负荷和悬浮固体导致二级处理效果不佳。采用扫描电子显微镜-能谱仪(SEM-EDS)分析了电凝聚过程中形成的污泥以及废水中污染物的去除机制。在不同操作条件(如pH值)下沉淀物的结构和组成表明,与使用相同剂量铝(Al)作为凝聚剂的化学凝聚相比,电凝聚提高了COD去除效率。电凝聚的COD去除效率为73.6%,化学凝聚为55.6%。电凝聚过程中原位形成沸石解释了与化学凝聚相比该处理方法的高效率。迄今为止,尚未见关于明胶生产厂废水电凝聚过程中沸石形成的报道。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1cd4/6543083/e600e912f1eb/gr1.jpg

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