Research Group for Nanocatalyst, Korea Research Institute of Chemical Technology (KRICT), P.O. Box 107, Yusung, Daejeon 305-600, South Korea.
J Nanosci Nanotechnol. 2019 Dec 1;19(12):8157-8162. doi: 10.1166/jnn.2019.16842.
Polyaniline (PA)-MOF nanocomposites have been successfully synthesized through an chemical oxidative polymerization of aniline in the presence of nano-sized iron trimestate (named as MIL-100(Fe)) particles, which was prepared by a microwave-irradiation method. Water sorption and humidity sensing results clearly showed that water sorption rate and humidity sensitivity are dramatically enhanced by the composites using nano-sized MIL-100(Fe) as compared with that using micrometer-sized MIL-100(Fe) particles.
聚苯胺(PA)-MOF 纳米复合材料已通过在纳米尺寸的三价铁(命名为 MIL-100(Fe))颗粒存在下苯胺的化学氧化聚合成功合成,该颗粒是通过微波辐射方法制备的。水吸附和湿度传感结果清楚地表明,与使用微米尺寸的 MIL-100(Fe)颗粒相比,使用纳米尺寸的 MIL-100(Fe)作为复合材料显著提高了水吸附率和湿度灵敏度。