Menéndez Esperanza, Argiz Cristina, Sanjuán Miguel Ángel
Instituto de Ciencias de la Construcción Eduardo Torroja (CSIC), C/Serrano Galvache, 4, 28033 Madrid, Spain.
Civil Engineering School, Technical University of Madrid, C/ProfesorAranguren, 3, Ciudad Universitaria, 28040 Madrid, Spain.
Materials (Basel). 2019 Jun 15;12(12):1933. doi: 10.3390/ma12121933.
Coal bottom ash is normally used as aggregate in mortars and concretes. When it is ground, its characteristics are modified. Therefore, the assessment of its long-term durability must be realized in depth. In this sense, an accelerated chloride ingress test has been performed on reinforced mortars made of Portland cement with different amounts of coal bottom ash (CBA) and/or coal fly ash (CFA). Corrosion potential and corrosion rate were continuously monitored. Cement replacement with bottom and fly ash had beneficial long-term effects regarding chloride penetration resistance. Concerning corrosion performance, by far the most dominant influencing parameter was the ash content. Chloride diffusion coefficient in natural test conditions decreased from 23 × 10 m/s in cements without coal ashes to 4.5 × 10 m/s in cements with 35% by weight of coal ashes. Moreover, the time to steel corrosion initiation went from 102 h to about 500 h, respectively. Therefore, this work presents experimental evidence that confirms the positive effect of both types of coal ashes (CBA and CFA) with regard to the concrete steel corrosion.
煤底灰通常用作砂浆和混凝土中的骨料。当其被磨细时,其特性会发生改变。因此,必须深入评估其长期耐久性。从这个意义上说,对由不同量的煤底灰(CBA)和/或粉煤灰(CFA)制成的波特兰水泥增强砂浆进行了加速氯离子侵入试验。持续监测腐蚀电位和腐蚀速率。用底灰和粉煤灰替代水泥对耐氯离子渗透性具有有益的长期影响。关于腐蚀性能,到目前为止,最主要的影响参数是灰分含量。在自然试验条件下,氯离子扩散系数从不含煤灰的水泥中的23×10⁻¹²m²/s降至含35%重量煤灰的水泥中的4.5×10⁻¹²m²/s。此外,钢铁开始腐蚀的时间分别从102小时增加到约500小时。因此,这项工作提供了实验证据,证实了两种类型的煤灰(CBA和CFA)对混凝土中钢铁腐蚀的积极影响。