P^P和P^N螯合金（I）的π配合物
π Complexes of P^P and P^N chelated gold(i).
作者信息
Navarro Miquel, Toledo Alberto, Joost Maximilian, Amgoune Abderrahmane, Mallet-Ladeira Sonia, Bourissou Didier
机构信息
Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069), Université de Toulouse, CNRS, 118 Route de Narbonne, 31062 Toulouse cedex 9, France.
Institut de Chimie de Toulouse (FR 2599), Université de Toulouse, CNRS, 118 route de Narbonne, 31062 Toulouse cedex 9, France.
出版信息
Chem Commun (Camb). 2019 Jul 14;55(55):7974-7977. doi: 10.1039/c9cc04266k. Epub 2019 Jun 21.
Tricoordinate gold(i) π-complexes containing P-based chelating ligands (P^P and P^N) were prepared. The structure of the gold(i) styrene complexes has been analysed in detail based on NMR and XRD data. The P^N complex is a competent catalyst for indole alkylation. The reaction proceeds with complete C3 and Markovnikov selectivity.
制备了含有基于磷的螯合配体（P^P和P^N）的三配位金（I）π配合物。基于核磁共振（NMR）和X射线衍射（XRD）数据，对金（I）苯乙烯配合物的结构进行了详细分析。P^N配合物是吲哚烷基化反应的有效催化剂。该反应以完全的C3选择性和马氏选择性进行。
Zotero 插件