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利用太赫兹时域光谱技术洞察含水矿物中的水状态。

Insights into the water status in hydrous minerals using terahertz time-domain spectroscopy.

作者信息

Ma Yuanyuan, Huang Haochong, Hao Sibo, Qiu Kunfeng, Gao Hua, Gao Lu, Tang Weichong, Zhang Zili, Zheng Zhiyuan

机构信息

School of Science, China University of Geosciences, Beijing, 100083, China.

School of Earth Science and Resources, China University of Geosciences, Beijing, 100083, China.

出版信息

Sci Rep. 2019 Jun 25;9(1):9265. doi: 10.1038/s41598-019-45739-2.

Abstract

The determinations of water status incorporated in hydrous minerals are of considerable significances in geoscience fields. Coincidentally, the aqueous sensitivity of terahertz radiation has motivated numerous explorations in several cross-domain applications. Terahertz time-domain spectroscopy is employed as a major probing technique coupling of traditional detecting methods to uncover the mask of water status in copper sulfate pentahydrate as well as mineral quartz in this article. Based on the quantitative identification of water status in copper sulfate pentahydrate, the water incorporated in mineral quartz is verified qualitatively. Notable differences of optical constants originating from the water content are obtained for copper sulfate pentahydrate and mineral quartz. These present works indicate that terahertz technology can be considered as a promising method to satisfy the ever-increasing requirements in hydrous mineral analyses.

摘要

含水矿物中水分状态的测定在地球科学领域具有相当重要的意义。巧合的是,太赫兹辐射对水的敏感性推动了在多个跨领域应用中的大量探索。本文采用太赫兹时域光谱作为主要探测技术,并结合传统检测方法,以揭示五水硫酸铜以及矿物石英中水分状态的奥秘。基于对五水硫酸铜中水分状态的定量识别,对矿物石英中所含的水进行了定性验证。五水硫酸铜和矿物石英因含水量不同而在光学常数上呈现出显著差异。这些研究成果表明,太赫兹技术有望满足对含水矿物分析日益增长的需求。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2594/6592908/e31c14ab87c9/41598_2019_45739_Fig1_HTML.jpg

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