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基于金属有机骨架的气相色谱分离。

Metal-Organic-Framework-based Gas Chromatographic Separation.

机构信息

Jiangsu Key Laboratory of Biofunctional Materials, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023, China.

出版信息

Chem Asian J. 2019 Oct 15;14(20):3462-3473. doi: 10.1002/asia.201900738. Epub 2019 Jul 31.

DOI:10.1002/asia.201900738
PMID:31294526
Abstract

Metal-organic frameworks (MOFs) have been applied in various fields because of their fascinating structures and excellent properties. MOFs can serve as stationary phases in gas chromatography (GC), which has led to exceptional improvements of performance. Here, we summarize the application of MOFs in GC based on the classification of analytes. The advantages and separation mechanism of MOFs as stationary phases in GC are discussed in combination with the characteristics and structures of MOFs. The limitations are also summarized in this review, which can provide prospects on further research for the applications of MOFs.

摘要

金属-有机骨架(MOFs)由于其迷人的结构和优异的性能,已被应用于各个领域。MOFs 可用作气相色谱(GC)中的固定相,从而导致性能的显著提高。在这里,我们根据分析物的分类总结了 MOFs 在 GC 中的应用。结合 MOFs 的特点和结构,讨论了 MOFs 作为 GC 中固定相的优点和分离机制。本文还总结了其局限性,为 MOFs 的应用提供了进一步研究的前景。

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