Dhbaibi Kais, Favereau Ludovic, Crassous Jeanne
ISCR (Institut des Sciences Chimiques de Rennes), UMR6226, CNRS , Université Rennes , F-35000 Rennes , France.
Faculty of Science of Gabès , University of Gabés , Zrig , 6072 Gabès Tunisia.
Chem Rev. 2019 Jul 24;119(14):8846-8953. doi: 10.1021/acs.chemrev.9b00033. Epub 2019 Jul 11.
In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-group elements. Enantioenriched helicenic derivatives containing main-group elements B, Si, N, and P, either incorporated within the helical backbone or grafted to it, will be thoroughly presented. We will describe their synthesis, resolution, and asymmetric synthesis, their structural features, electronic and chiroptical properties, and emission, together with other photochemical properties and applications.
在本综述中，我们讨论了含主族元素的螺旋烯和类螺旋烯的丰富化学性质。将全面介绍在螺旋主链中引入或接枝有主族元素硼、硅、氮和磷的对映体富集螺旋烯衍生物。我们将描述它们的合成、拆分和不对称合成、结构特征、电子和手性光学性质、发光，以及其他光化学性质和应用。
