Isosaari Pirjo, Srivastava Varsha, Sillanpää Mika
Department of Green Chemistry, School of Engineering Science, Lappeenranta-Lahti University of Technology, Sammonkatu 12, FI-50130 Mikkeli, Finland.
Department of Green Chemistry, School of Engineering Science, Lappeenranta-Lahti University of Technology, Sammonkatu 12, FI-50130 Mikkeli, Finland.
Sci Total Environ. 2019 Nov 10;690:604-619. doi: 10.1016/j.scitotenv.2019.06.421. Epub 2019 Jun 29.
Water scarcity motivated the scientific researcher to develop efficient technologies for the wastewater treatment for its reuse. Ionic liquids have been applied to many industrial and analytical separation processes, but their applications in the wastewater treatment, especially in the removal of organic pollutants, are still not well explored. Potential applications of ionic liquids include solvent extraction, solvent membrane technologies and ionic liquid-modified materials that are mainly used as adsorbents. Aforementioned technologies have been examined for the abatement of phenol, chloro- and nitrophenols, toluene, bisphenol A, phthalates, pesticides, dyes, and pharmaceuticals etc. Present review enlightens the application of different ionic liquids in wastewater treatment and suggests the versatility of ionic liquids in the development of rapid, effective and selective removal processes for the variety of organic pollutants. Implementation of ionic liquid based technologies for wastewater treatment have lots of challenges including the selection of non-hazardous ionic liquids, technological applications, high testing requirements for individual uses and scaling-up of the entire pollutant removal, disposal, and ionic liquid regeneration process. Toxicity assessment of water soluble ionic liquids (ILs) is the major issue due to the widespread application of ILs and hence more exposure of environment by ILs. The development of effective technologies for the recovery/treatment of wastewater contaminated with ILs is necessary from the environmental point of view. Furthermore, the cost factor is the major challenge associated with ionic liquid-based technologies.
水资源短缺促使科研人员开发高效的废水处理技术以实现水的再利用。离子液体已应用于许多工业和分析分离过程,但其在废水处理中的应用,尤其是在去除有机污染物方面,仍未得到充分探索。离子液体的潜在应用包括溶剂萃取、溶剂膜技术以及主要用作吸附剂的离子液体改性材料。上述技术已被用于去除苯酚、氯酚和硝基酚、甲苯、双酚A、邻苯二甲酸盐、农药、染料和药物等。本综述阐述了不同离子液体在废水处理中的应用,并表明离子液体在开发针对各种有机污染物的快速、有效和选择性去除工艺方面具有多功能性。基于离子液体的废水处理技术的实施面临诸多挑战,包括选择无害离子液体、技术应用、针对个别用途的高测试要求以及扩大整个污染物去除、处置和离子液体再生过程的规模。由于离子液体的广泛应用,水溶性离子液体的毒性评估成为主要问题,因此离子液体对环境的暴露更多。从环境角度来看,开发有效的技术来回收/处理受离子液体污染的废水是必要的。此外,成本因素是与基于离子液体的技术相关的主要挑战。