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Carba-closo-dodecaboranylethynyl ligands facilitating luminescent reversed charge-transfer excited states in gold/silver complexes.

作者信息

Hailmann Michael, Hupp Benjamin, Himmelspach Alexander, Keppner Fabian, Hennig Philipp T, Bertermann Rüdiger, Steffen Andreas, Finze Maik

机构信息

Institut für Anorganische Chemie, Institut für nachhaltige Chemie & Katalyse mit Bor (ICB), Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Str. 6, 44227 Dortmund, Germany.

出版信息

Chem Commun (Camb). 2019 Aug 14;55(63):9351-9354. doi: 10.1039/c9cc05060d. Epub 2019 Jul 17.

DOI:10.1039/c9cc05060d
PMID:31313764
Abstract

A set of mono- and dinuclear Au and Ag alkynyl complexes bearing the carba-closo-dodecaboranylethynyl ligand show intense room temperature phosphorescence. The {closo-1-CB} cage participates in an unprecedented way as an electron donating moiety, changing the direction of the charge-transfer excited state.

摘要

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