Fujihara Tetsuaki, Tsuji Yasushi
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan.
Front Chem. 2019 Jun 27;7:430. doi: 10.3389/fchem.2019.00430. eCollection 2019.
The use of carbon dioxide (CO) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of organic substrates with CO via allyl metal intermediates. First, carboxylation reactions via transmetalation are reviewed. Second, catalytic carboxylation reactions using allyl electrophiles and suitable reducing agents are summarized. The last section discusses the catalytic carboxylation reactions via addition reactions, affording allyl metal intermediates.
就当前气候研究和地球环境而言，二氧化碳（CO）的使用是一个重要问题。使用CO的过渡金属催化羧化反应极具吸引力。本综述总结了通过烯丙基金属中间体实现的有机底物与CO的过渡金属催化羧化反应。首先，综述了通过金属转移进行的羧化反应。其次，总结了使用烯丙基亲电试剂和合适还原剂的催化羧化反应。最后一部分讨论了通过加成反应生成烯丙基金属中间体的催化羧化反应。
