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采用曝气和好氧区与非曝气区共存的复合膜曝气生物反应器强化处理乙腈废水。

Acetonitrile wastewater treatment enhanced by a hybrid membrane-aerated bioreactor containing aerated and non-aerated zones.

机构信息

College of Biology and the Environment, Nanjing Forestry University, Nanjing 210037, China.

College of Biology and the Environment, Nanjing Forestry University, Nanjing 210037, China.

出版信息

Bioresour Technol. 2019 Oct;289:121754. doi: 10.1016/j.biortech.2019.121754. Epub 2019 Jul 3.

DOI:10.1016/j.biortech.2019.121754
PMID:31323714
Abstract

Acetonitrile (ACN) is a very volatile, toxic and nitrogen-rich organic compound. To enhance ACN wastewater treatment, a novel hybrid membrane-aerated bioreactor (MAB) containing aerated and non-aerated zones was established. A polypropylene hollow fiber membrane module (HF) and a silicone rubber membrane module (SR) were separately used as the bubble-free aeration diffuser and the biofilm carrier, and the non-aerated zones of these two types of reactors were packed with ceramsite. When the influent ACN loading was 1.200 kg/m·d, under aeration pressures of 20 kPa in the HF-MAB and 40 kPa in the SR-MAB, ACN removal loadings of 1.116 kg/m·d and 1.004 kg/m·d, respectively, were achieved, and the TN (total nitrogen) removal loadings were 0.267 kg/m·d and 0.246 kg/m·d, respectively. In the MABs, different stratified biofilm structures of the two zones and the diffusion and counter-diffusion of oxygen synergistically promoted ACN degradation, nitrification and denitrification.

摘要

乙腈(ACN)是一种挥发性很强、毒性很大且富含氮的有机化合物。为了增强乙腈废水处理效果,构建了一种新型的含曝气区和非曝气区的混合膜曝气生物反应器(MAB)。分别使用聚丙烯中空纤维膜组件(HF)和硅橡胶膜组件(SR)作为无泡曝气扩散器和生物膜载体,这两种类型的反应器的非曝气区均填充陶粒。当进水 ACN 负荷为 1.200kg/m·d 时,在 HF-MAB 中曝气压力为 20kPa 和在 SR-MAB 中曝气压力为 40kPa 的条件下,分别实现了 1.116kg/m·d 和 1.004kg/m·d 的 ACN 去除负荷,以及 0.267kg/m·d 和 0.246kg/m·d 的总氮(TN)去除负荷。在 MAB 中,两个区的不同分层生物膜结构以及氧气的扩散和反扩散协同促进了 ACN 的降解、硝化和反硝化。

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