Effective treatment and utilization of hazardous waste sulfuric acid generated from alkylation by lignocellulose ester-catalyzed oxidative degradation of organic pollutants.

Alkylation reaction catalyzed by concentrated HSO generates hazardous waste HSO containing a large amount of organic pollutants. This study focused on effective utilization and treatment of the waste HSO for simultaneous consumption of HSO and deep oxidative degradation of the organics. The waste HSO could completely react with magnesium oxide ore to prepare crude MgSO solution, and the organic pollutants in the solution were deeply degraded and mainly mineralized to HO and CO with HO as oxidant and sugarcane bagasse citrate (SBC), a kind of lignocellulose ester, as catalyst. The total amount of acidic groups of SBC significantly affected its catalytic activity, attributing to that these oxygen-containing functional groups adsorbed and immobilized metal ions on SBC to form catalytic active sites, which could activate and catalyze HO to generate •OH and HO• radicals for effective degradation of the organics. The resulting purified MgSO solution with color removal of 93.71% and total organic carbon removal of 85.89% under optimum catalytic reaction conditions was used to produce qualified MgSO∙7HO product. These results highlighted the feasibility of using lignocellulose ester as effective catalyst for deep oxidative degradation of hazardous organic pollutants.