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对称化学活性粒子的自推进:点源模型与樟脑盘实验

Self-propulsion of symmetric chemically active particles: Point-source model and experiments on camphor disks.

作者信息

Boniface Dolachai, Cottin-Bizonne Cécile, Kervil Ronan, Ybert Christophe, Detcheverry François

机构信息

Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière, F-69622 Villeurbanne, France.

出版信息

Phys Rev E. 2019 Jun;99(6-1):062605. doi: 10.1103/PhysRevE.99.062605.

Abstract

Solid undeformable particles surrounded by a liquid medium or interface may propel themselves by altering their local environment. Such nonmechanical swimming is at work in autophoretic swimmers, whose self-generated field gradient induces a slip velocity on their surface, and in interfacial swimmers, which exploit unbalance in surface tension. In both classes of systems, swimmers with intrinsic asymmetry have received the most attention but self-propulsion is also possible for particles that are perfectly isotropic. The underlying symmetry-breaking instability has been established theoretically for autophoretic systems but has yet to be observed experimentally for solid particles. For interfacial swimmers, several experimental works point to such a mechanism, but its understanding has remained incomplete. The goal of this work is to fill this gap. Building on an earlier proposal, we first develop a point-source model that may be applied generically to interfacial or phoretic swimmers. Using this approximate but unifying picture, we show that they operate in very different regimes and obtain analytical predictions for the propulsion velocity and its dependence on swimmer size and asymmetry. Next, we present experiments on interfacial camphor disks showing that they indeed self-propel in an advection-dominated regime where intrinsic asymmetry is irrelevant and that the swimming velocity increases sublinearly with size. Finally, we discuss the merits and limitations of the point-source model in light of the experiments and point out its broader relevance.

摘要

被液体介质或界面包围的固态不可变形颗粒可以通过改变其局部环境来推动自身运动。这种非机械游动在自泳体中发挥作用,自泳体自身产生的场梯度会在其表面诱导出滑移速度;在界面泳体中也存在这种现象,界面泳体利用表面张力的不平衡来实现游动。在这两类系统中,具有内在不对称性的泳体受到了最多关注,但对于完全各向同性的颗粒来说,自我推进也是可能的。自泳系统中,潜在的对称破缺不稳定性已在理论上得到确立,但对于固体颗粒,尚未通过实验观察到。对于界面泳体,一些实验工作指向了这样一种机制,但其理解仍不完整。这项工作的目标就是填补这一空白。基于早期的一个提议,我们首先开发了一个点源模型,该模型可普遍应用于界面泳体或电泳泳体。利用这个近似但统一的图景,我们表明它们在非常不同的 regime 下运行,并得到了推进速度及其对泳体尺寸和不对称性的依赖性的解析预测。接下来,我们展示了关于界面樟脑盘的实验,表明它们确实在对流主导的 regime 中自我推进,在这个 regime 中内在不对称性无关紧要,并且游动速度随尺寸呈亚线性增加。最后,我们根据实验讨论了点源模型的优缺点,并指出其更广泛的相关性。

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