Sodreau Alexandre, Lentz Nicolas, Frutos Maria, Mallet-Ladeira Sonia, Nayral Céline, Delpech Fabien, Madec David
Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069), Université de Toulouse, CNRS, 118 Route de Narbonne, F-31062 Toulouse, France.
Chem Commun (Camb). 2019 Aug 7;55(64):9539-9542. doi: 10.1039/c9cc05063a.
We report herein the synthesis of symmetric and non-symmetric bis-amidinato-germylene Fe(CO)3 complexes, as well as the preparation of the corresponding disymmetric germylene-stannylene and germylene-silylene complexes by selective displacement of a carbonyl ligand under UV-a light irradiation. The symmetric bis-germylene Fe(CO)3 complex has been applied in the synthesis of iron germanide nanocrystals.
我们在此报告对称和非对称双脒基锗烯铁（CO）₃配合物的合成，以及通过在紫外光照射下选择性取代羰基配体制备相应的不对称锗烯-亚锡烯和锗烯-亚硅烯配合物。对称双锗烯铁（CO）₃配合物已应用于锗化铁纳米晶体的合成。
